Toggle Main Menu Toggle Search

Open Access padlockePrints

Rhodium Complexes of (R)-Me-CATPHOS and (R)-(S)-JOSIPHOS: Highly Enantioselective Catalysts for the Asymmetric Hydrogenation of (E)- and (Z)-beta-Aryl-beta-(Enamido)phosphonates

Lookup NU author(s): Dr Simon DohertyORCiD, Dr Julian Knight, Adam Bell

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

Rhodium complexes of (R)-Me-CATPHOS and (R)-(S)-JOSIPHOS form a complimentary pair of catalysts for the highly efficient asymmetric hydrogenation of (E)- and (Z)-beta-aryl-beta-(enamido)phosphonates, in each case giving excellent yields and ee’s in excess of 99%, the highest to be reported for this class of substrate.


Publication metadata

Author(s): Doherty S, Knight JG, Bell AL, El-Menabawey S, Westcott S

Publication type: Article

Publication status: Published

Journal: Tetrahedron: Asymmetry

Year: 2009

Volume: 20

Issue: 12

Pages: 1437-1444

ISSN (print): 0957-4166

ISSN (electronic): 1362-511X

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/j.tetasy.2009.05.023

DOI: 10.1016/j.tetasy.2009.05.023


Altmetrics

Altmetrics provided by Altmetric


Share