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Selective rhodium(III)-catalyzed cross-dehydrogenative coupling of furan and thiophene derivatives

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

A hot couple: An unprecedented rhodium(III)-catalyzed cross-dehydrogenative coupling (CDC) of various furan and thiophene derivatives leads to valuable 2,2'-bi(heteroaryl) products in good yields and selectivities (see scheme). In addition, pyrroles and indoles can also be used as coupling partners, giving C3-arylated products. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Publication metadata

Author(s): Kuhl N, Hopkinson MN, Glorius F

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie - International Edition

Year: 2012

Volume: 51

Issue: 33

Pages: 8230-8234

Print publication date: 13/08/2012

Online publication date: 06/07/2012

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley

URL: https://doi.org/10.1002/anie.201203792

DOI: 10.1002/anie.201203792

PubMed id: 22777710

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