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Anionic chiral cobalt(III) complexes as catalysts of asymmetric synthesis of cyanohydrins

Lookup NU author(s): Dmitry Usanov, Professor Michael North

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Abstract

Chiral coordinatively saturated cobalt(III) complexes with Schiff bases of enantio-pure amino acids are formed as Λ and Δ-isomers, which are not transformed into each other under normal conditions. These complexes catalyze the formation of enantiomerically enriched cyanohydrins from aldehydes and Me3SiCN under homo-and heterogeneous catalysis. © Springer Science+Business Media, Inc. 2006.

Publication metadata

Author(s): Belokon YuN, Maleev VI, Mal'Fanov IL, Savel'Eva TF, Ikonnikov NS, Bulychev AG, Usanov DL, Kataev DA, North M

Publication type: Article

Publication status: Published

Journal: Russian Chemical Bulletin

Year: 2006

Volume: 55

Issue: 5

Pages: 821-827

ISSN (print): 1066-5285

ISSN (electronic): 1573-9171

Publisher: Springer

URL: http://dx.doi.org/10.1007/s11172-006-0338-4

DOI: 10.1007/s11172-006-0338-4

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