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Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: Connections to ring-stacking, ring-laddering, and inverse crown concepts

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Sophie Dale, Dr Ross Harrington

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Abstract

The first sodium-magnesium and sodium-zinc ketimido complexes display contrasting inverse crown ring and pseudo-cubane structures respectively, while a sodium-zinc heterotrianionic alkide-alkoxide-amide adopts a third type of structure with a stepped ladder motif. © The Royal Society of Chemistry.

Publication metadata

Author(s): Clegg W, Dale SH, Graham DV, Harrington RW, Hevia E, Hogg LM, Kennedy AR, Mulvey RE

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2007

Issue: 16

Pages: 1641-1643

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b618609b

DOI: 10.1039/b618609b

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