Catalyst initiation in the oscillatory carbonylation reaction

  1. Lookup NU author(s)
  2. Dr Katarina Novakovic
  3. Julie Parker
Author(s)Novakovic K, Parker J
Publication type Article
JournalInternational Journal of Chemical Engineering
Year2011
Volume2011
Issue
Pages
ISSN (print)1687-806X
ISSN (electronic)1687-8078
Full text is available for this publication:
Palladium(II) iodide is used as a catalyst in the phenylacetylene oxidative carbonylation reaction that has demonstrated oscillatory behaviour in both pH and heat of reaction. In an attempt to extract the reaction network responsible for the oscillatory nature of this reaction, the system was divided into smaller parts and they were studied. This paper focuses on understanding the reaction network responsible for the initial reactions of palladium(II) iodide within this oscillatory reaction. The species researched include methanol, palladium(II) iodide, potassium iodide, and carbon monoxide. Several chemical reactions were considered and applied in a modelling study. The study revealed the significant role played by traces of water contained in the standard HPLC grade methanol used.
PublisherHindawi Publishing Corporation
URLhttp://dx.doi.org/10.1155/2011/518592
DOI10.1155/2011/518592
NotesArticle ID 518592, 11 pages
Actions    Link to this publication
Share