An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation

  1. Lookup NU author(s)
  2. Dr Simon Doherty
  3. Dr Julian Knight
  4. Jack Ellison
  5. Dr Ross Harrington
Author(s)Doherty S, Knight JG, Ellison J, Weekes D, Harrington RW, Hardacre C, Manyer H
Publication type Article
JournalGreen Chemistry
ISSN (print)1463-9262
ISSN (electronic)1463-9270
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Ring Opening Metathesis Polymerisation (ROMP) of pyrrolidinium-functionalised norbornene-based monomers with cyclooctene has been used to prepare linear cation-decorated polymer supports with tuneable surface properties and microstructure. The derived peroxophosphotungstate-based polymer immobilised ionic liquid phase (PIILP) catalyst is an efficient and recyclable system for the epoxidation of allylic alcohols and alkenes, with only a minor reduction in performance on successive cycles.
PublisherRoyal Society of Chemistry
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