An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation

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  2. Dr Simon Doherty
  3. Dr Julian Knight
  4. Jack Ellison
  5. Dr Ross Harrington
Author(s)Doherty S, Knight JG, Ellison J, Weekes D, Harrington RW, Hardacre C, Manyer H
Publication type Article
JournalGreen Chemistry
Year2012
Volume14
Issue4
Pages925-929
ISSN (print)1463-9262
ISSN (electronic)1463-9270
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Ring Opening Metathesis Polymerisation (ROMP) of pyrrolidinium-functionalised norbornene-based monomers with cyclooctene has been used to prepare linear cation-decorated polymer supports with tuneable surface properties and microstructure. The derived peroxophosphotungstate-based polymer immobilised ionic liquid phase (PIILP) catalyst is an efficient and recyclable system for the epoxidation of allylic alcohols and alkenes, with only a minor reduction in performance on successive cycles.
PublisherRoyal Society of Chemistry
URLhttp://dx.doi.org/10.1039/C2GC16679H
DOI10.1039/C2GC16679H
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