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Orthogonal breaking and forming of dynamic covalent imine and disulfide bonds in aqueous solution

Lookup NU author(s): Michael Bracchi, Dr David Fulton

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).


Abstract

Orthogonal bond-breaking and forming of dynamic covalent disulfide and imine bonds in aqueous solution is demonstrated. Through judicious choice of reaction partners and conditions, it is possible to cleave and reform selectively these bonds in the presence of each other in the absence of unwanted competing processes.


Publication metadata

Author(s): Bracchi ME, Fulton DA

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2015

Volume: 51

Issue: 55

Pages: 11052-11055

Print publication date: 14/07/2015

Online publication date: 05/06/2015

Acceptance date: 05/06/2015

Date deposited: 13/11/2015

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/C5CC02716K

DOI: 10.1039/C5CC02716K


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