Highly Luminescent Cesium Lead Halide Perovskite Nanocrystals with Tunable Composition and Thickness by Ultrasonication

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  2. Dr Pablo Docampo
Author(s)Tong Y, Bladt E, Aygueler MF, Manzi A, Milowska KZ, Hintermayr VA, Docampo P, Bals S, Urban AS, Polavarapu L, Feldmann J
Publication type Article
JournalAngewandte Chemie International Edition
Year2016
Volume55
Issue44
Pages13887-13892
ISSN (print)1433-7851
ISSN (electronic)1521-3773
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We describe the simple, scalable, single-step, and polar-solvent-free synthesis of high-quality colloidal CsPbX3 (X=Cl, Br, and I) perovskite nanocrystals (NCs) with tunable halide ion composition and thickness by direct ultrasonication of the corresponding precursor solutions in the presence of organic capping molecules. High angle annular dark field scanning transmission electron microscopy (HAADF-STEM) revealed the cubic crystal structure and surface termination of the NCs with atomic resolution. The NCs exhibit high photoluminescence quantum yields, narrow emission line widths, and considerable air stability. Furthermore, we investigated the quantum size effects in CsPbBr3 and CsPbI3 nanoplatelets by tuning their thickness down to only three to six monolayers. The high quality of the prepared NCs (CsPbBr3) was confirmed by amplified spontaneous emission with low thresholds. The versatility of this synthesis approach was demonstrated by synthesizing different perovskite NCs.
PublisherWiley-Blackwell Publishing Ltd.
URLhttp://dx.doi.org/10.1002/anie.201605909
DOI10.1002/anie.201605909
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