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Addition of phenylisocyanate to 3,5-diphenyl-1,2-dithiolium-4-olate gives a thioketone

Lookup NU author(s): Professor Mike ProbertORCiD

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Abstract

© 2017 Elsevier Ltd The Type B mesoionic heterocycle, 3,5-diphenyl-1,2-dithiolium-4-olate, reacts with phenylisocyanate producing a thioketone derivative rather than a pseudo-semi-conjugated heterocyclic mesomeric betaine. The structure of the thioketone product was confirmed by an X-ray crystallographic investigation.

Publication metadata

Author(s): Probert MR, Ramsden CA, Stanforth SP

Publication type: Article

Publication status: Published

Journal: Tetrahedron Letters

Year: 2017

Volume: 58

Issue: 14

Pages: 1425-1427

Print publication date: 05/04/2017

Online publication date: 27/02/2017

Acceptance date: 24/02/2017

ISSN (print): 0040-4039

ISSN (electronic): 1873-3581

Publisher: Elsevier Ltd

URL: https://doi.org/10.1016/j.tetlet.2017.02.076

DOI: 10.1016/j.tetlet.2017.02.076

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