Regioselective Addition of tert-BuNC to the α Carbon Atom of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η1:η2α,β-(H)CαCβCγH2}]: Formation of [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)CCCH3}] and [Fe2(CO)6(μ-PPh2)(μ-η1:η2-{tert-BuNHC(O)CH2}CCH2)] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)HCCCH2}]

  1. Lookup NU author(s)
  2. Dr Simon Doherty
  3. Mark Waugh
  4. Thomas Scanlan
  5. Emeritus Professor William Clegg
  6. Dr Mark Elsegood
Author(s)Doherty S, Hogarth G, Waugh M, Scanlan TH, Clegg W, Elsegood MRJ
Publication type Article
JournalOrganometallics
Year1999
Volume18
Issue16
Pages3178-3186
ISSN (print)0276-7333
ISSN (electronic)1520-6041
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
PublisherAmerican Chemical Society
URLhttp://dx.doi.org/10.1021/om9901630
DOI10.1021/om9901630
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