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Covalent immobilization of a TiW₅ polyoxometalate on derivatized silicon surfaces

Lookup NU author(s): Dr John ErringtonORCiD, Dr Ben Horrocks, Professor Andrew HoultonORCiD

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Abstract

Covalent ties: The polyoxometalate (nBu4N)3[(MeO) TiW5O18] is easily anchored to alkanol-functionalized surfaces of porous and single-crystal silicon (see picture, polyhedra: polyoxometalate, dark blue: Si surface). Scanning tunneling microscopy reveals the growth of 35-50 nm diameter islands on functionalized Si(111), which suggests that the immobilized polyoxometalates act as nucleation sites for electrostatic aggregation. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Publication metadata

Author(s): Errington RJ, Petkar SS, Horrocks BR, Houlton A, Lie LH, Patole SN

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie - International Edition

Year: 2005

Volume: 44

Issue: 8

Pages: 1254-1257

Print publication date: 11/02/2005

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley

URL: http://dx.doi.org/10.1002/anie.200461065

DOI: 10.1002/anie.200461065

PubMed id: 15696586

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