Toggle Main Menu Toggle Search

Open Access padlockePrints

Oxidation reactions of a phosphine-borane-stabilised dialkylstannylene

Lookup NU author(s): Dr Corinne Wills, Dr Keith Izod, Emeritus Professor Bill Clegg, Dr Ross Harrington

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

The acyclic dialkylstannylene [(Me3Si){Me2P(BH3)}CH](2)Sn (7) reacts with any of methyl iodide, neopentyl iodide or benzyl bromide to yield the corresponding oxidative addition products [(Me3Si){Me2P(BH3)}CH](2)Sn(Me)(I) (8), [(Me3Si){Me2P(BH3)}CH] Sn-2(CH2CMe3)(I) (9), and [(Me3Si){Me2P(BH3)}CH](2)Sn(CH2Ph)(Br) (10), respectively. The crystal structures of 8, 9, and 10 reveal that there are no close B-H center dot center dot center dot Sn contacts. In addition, 7 reacts with benzil or elemental sulfur to yield [{Me2P(BH3)}(Me3Si)CH](2)Sn(OCPh=CPhO) (11) and [{Me2P(BH3)}(Me3Si)CH](2)Sn(S) (12), respectively, as confirmed by multinuclear NMR spectroscopy and elemental analysis.


Publication metadata

Author(s): Wills C, Izod K, Clegg W, Harrington RW

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2010

Volume: 39

Issue: 9

Pages: 2379-2384

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b922507b

DOI: 10.1039/b922507b


Altmetrics

Altmetrics provided by Altmetric


Actions

Find at Newcastle University icon    Link to this publication


Share