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Oxidation reactions of a phosphine-borane-stabilised dialkylstannylene

Lookup NU author(s): Dr Corinne Wills, Dr Keith Izod, Emeritus Professor Bill CleggORCiD, Dr Ross Harrington

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Abstract

The acyclic dialkylstannylene [(Me3Si){Me2P(BH3)}CH](2)Sn (7) reacts with any of methyl iodide, neopentyl iodide or benzyl bromide to yield the corresponding oxidative addition products [(Me3Si){Me2P(BH3)}CH](2)Sn(Me)(I) (8), [(Me3Si){Me2P(BH3)}CH] Sn-2(CH2CMe3)(I) (9), and [(Me3Si){Me2P(BH3)}CH](2)Sn(CH2Ph)(Br) (10), respectively. The crystal structures of 8, 9, and 10 reveal that there are no close B-H center dot center dot center dot Sn contacts. In addition, 7 reacts with benzil or elemental sulfur to yield [{Me2P(BH3)}(Me3Si)CH](2)Sn(OCPh=CPhO) (11) and [{Me2P(BH3)}(Me3Si)CH](2)Sn(S) (12), respectively, as confirmed by multinuclear NMR spectroscopy and elemental analysis.

Publication metadata

Author(s): Wills C, Izod K, Clegg W, Harrington RW

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2010

Volume: 39

Issue: 9

Pages: 2379-2384

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b922507b

DOI: 10.1039/b922507b

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