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New chiral organosulfur donors related to bis(ethylenedithio)tetrathiafulvalene

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Ross Harrington, Dr Luca Russo

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Abstract

Six new enantiopure chiral organosulfur donors, with structures related to BEDT-TTF, have been synthesised for use in the preparation of organic metals, starting either by double nucleophilic substitutions on the bis-mesylate of 2R,4R-pentane-2,4-diol or by a cycloaddition with subsequent elimination of acetic acid on the enol acetate of (+)-nopinone. Crystal structures of some of their radical cation triiodides salts and TCNQ complexes are reported. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.

Publication metadata

Author(s): Yang SJ, Brooks AC, Martin L, Day P, Pilkington M, Clegg W, Harrington RW, Russo L, Wallis JD

Publication type: Article

Publication status: Published

Journal: Tetrahedron

Year: 2010

Volume: 66

Issue: 34

Pages: 6977-6989

Print publication date: 18/06/2010

ISSN (print): 0040-4020

ISSN (electronic): 1464-5416

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/j.tet.2010.06.034

DOI: 10.1016/j.tet.2010.06.034

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