Lookup NU author(s): Professor Allen Wright
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Rather than proceeding through a Michael-type or 1,4-addition, thioacetic acid adds across unsaturated aldehydes in an autocatalytic manner and involving a double exotherm, as demonstrated by both adiabatic and reaction calorimetry. NMR studies show that an intermediate acyl-thio-hemiacetal is involved and that the product continues to react competitively with thioacetic acid. © 2010 Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim.
Author(s): Ilyashenko G, Whiting A, Wright A
Publication type: Article
Publication status: Published
Journal: Advanced Synthesis & Catalysis
Print publication date: 16/08/2010
ISSN (print): 1615-4150
ISSN (electronic): 1615-4169
Publisher: Wiley - VCH Verlag GmbH & Co. KGaA
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