Lookup NU author(s): Dr Simon Doherty
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The synthesis of phosphinoboronate esters containing a single B-P bond is reported herein, along with preliminary reactivity studies with a number of organic substrates. These compounds add readily to aldehydes, ketones, aldimines, and α,β-unsaturated enones to give primarily the corresponding 1,2-addition products containing a new P-C bond. The first examples of the transition metal catalysed phosphinoboration of allenes and terminal alkynes are also reported.
Author(s): Daley EN, Vogels CM, Geier SJ, Decken A, Doherty S, Westcott SA
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie International Edition
Print publication date: 09/02/2015
Online publication date: 30/12/2014
Acceptance date: 18/11/2014
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
Publisher: Wiley - V C H Verlag GmbH & Co. KGaA
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