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The Phosphinoboration Reaction

Lookup NU author(s): Dr Simon DohertyORCiD

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Abstract

The synthesis of phosphinoboronate esters containing a single B-P bond is reported herein, along with preliminary reactivity studies with a number of organic substrates. These compounds add readily to aldehydes, ketones, aldimines, and α,β-unsaturated enones to give primarily the corresponding 1,2-addition products containing a new P-C bond. The first examples of the transition metal catalysed phosphinoboration of allenes and terminal alkynes are also reported.

Publication metadata

Author(s): Daley EN, Vogels CM, Geier SJ, Decken A, Doherty S, Westcott SA

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie International Edition

Year: 2015

Volume: 54

Issue: 7

Pages: 2121-2125

Print publication date: 09/02/2015

Online publication date: 30/12/2014

Acceptance date: 18/11/2014

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - V C H Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.201410033

DOI: 10.1002/anie.201410033

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