Lookup NU author(s): Dr Mike Probert
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
1-Phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e] [1,2,4]triazin-4-yl is the first example of a hydrazyl radical that shows a reversible sharp spin transition fully completed within 5(1) K. The nominally first-order transition takes place at ca. 58(2) K and proceeds via subtle changes of intra- and interstack interactions between two similar structural phases. The low-temperature phase (5-60 K) is diamagnetic and has a singlet ground state (2J(exp) = -166.8 cm(-1), g(solid) = 2.0042, rho = 0.2%) stemming from a multicenter two-electron interaction. The high-temperature phase (60-300 K) is paramagnetic as a result of noninteracting S = 1/2 spins arising from weakly bound dimers.
Author(s): Constantinides CP, Berezin AA, Zissimou GA, Manoli M, Leitus GM, Bendikov M, Probert MR, Rawson JM, Koutentis PA
Publication type: Article
Publication status: Published
Journal: Journal of the American Chemical Society
Print publication date: 27/08/2014
Online publication date: 05/08/2014
Acceptance date: 25/06/2014
ISSN (print): 0002-7863
ISSN (electronic): 1520-5126
Publisher: American Chemical Society
Altmetrics provided by Altmetric