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Low-temperature and high-pressure polymorphs of isopropyl alcohol

Lookup NU author(s): Joe Ridout, Dr Mike Probert

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Abstract

Single-crystal X-ray diffraction has been used to elucidate the structure of two polymorphs of isopropyl alcohol, one grown through in situ cryo-crystallisation, the other through high-pressure crystallisation. The packing in both structures is dominated by O-H center dot center dot center dot O hydrogen bonds, with the high-pressure polymorph being significantly more dense than the low-temperature structure.


Publication metadata

Author(s): Ridout J, Probert MR

Publication type: Article

Publication status: Published

Journal: CrystEngComm

Year: 2014

Volume: 16

Issue: 32

Pages: 7397-7400

Print publication date: 28/08/2014

Online publication date: 25/06/2014

Acceptance date: 24/06/2014

ISSN (electronic): 1466-8033

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/c4ce01012d

DOI: 10.1039/c4ce01012d


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