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Potassium-alkyl magnesiates: synthesis, structures and Mg-H exchange applications of aromatic and heterocyclic substrates

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Luca Russo

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Abstract

Using structurally well-defined dipotassium-tetra(alkyl)magnesiates, a new straightforward methodology to promote regioselective Mg-H exchange reactions of a wide range of aromatic and heteroaromatic substrates is disclosed. Contacted ion pair intermediates are likely to be involved, with K being the key to facilitate the magnesiation processes.

Publication metadata

Author(s): Baillie SE, Bluemke TD, Clegg W, Kennedy AR, Klett J, Russo L, de Tullio M, Hevia E

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2014

Volume: 50

Issue: 85

Pages: 12859-12862

Print publication date: 04/11/2014

Online publication date: 03/09/2014

Acceptance date: 02/09/2014

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: RSC Publications

URL: http://dx.doi.org/10.1039/c4cc05305b

DOI: 10.1039/c4cc05305b

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