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A high-pressure crystallographic and magnetic study of Na-5[Mn(L-tart)2].12H2O (L-tart = L-tartrate)

Lookup NU author(s): Dr Mike Probert

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Abstract

The crystal structure and magnetic properties of the compound Na-5[Mn(L-tart)2]center dot 12H(2)O ( 1, L-tart = L-tartrate) have been investigated over the pressure range 0.34-3.49 GPa. The bulk modulus of 1 has been determined as 23.9(6) GPa, with a compression of the coordination spheres around the Na+ ions observed. 1 is therefore relatively incompressible, helping it to retain its magnetic anisotropy under pressure.


Publication metadata

Author(s): Craig GA, Woodall CH, McKellar SC, Probert MR, Kamenev KV, Moggach SA, Brechin EK, Parsons S, Murrie M

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2015

Volume: 44

Issue: 42

Pages: 18324-18328

Print publication date: 14/11/2015

Online publication date: 30/09/2015

Acceptance date: 29/09/2015

Date deposited: 20/04/2016

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/C5DT03320A

DOI: 10.1039/c5dt03320a


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