Lookup NU author(s): Dr Katarina Novakovic
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0).
Over the past two decades the oscillatory nature of the PdI2-catalysed oxidative carbonylation of phenylacetylene has been experimentally studied and reproducible oscillations in pH were reported. Oscillatory behaviour has been reported over the temperature range 0-40 °C under batch or semi-batch conditions. Recently, oscillatory palladium-catalysed carbonylation has been achieved using mono alkyne-terminated poly(ethylene glycol) methyl ether at 20 °C demonstrating that alkyne-terminated macromolecules are also suitable substrates. In this work, studies of both oscillatory systems (phenylacetylene and mono alkyne-terminated poly(ethylene glycol) methyl ether) conducted in a 1 litre automated reactor system are reported.
Author(s): Novakovic K, Nwosu JC, Parker J
Editor(s): Zeljko Cupic and Slobodan Anic
Publication type: Conference Proceedings (inc. Abstract)
Publication status: Published
Conference Name: Physical Chemistry 2016, 13th International Conference on Fundamental and Applied Aspects of Physical Chemistry
Year of Conference: 2016
Number of Volumes: 2
Print publication date: 26/09/2016
Online publication date: 26/09/2016
Acceptance date: 15/06/2016
Date deposited: 18/10/2016
Publisher: Society of Physical Chemists of Serbia
Library holdings: Search Newcastle University Library for this item