Lookup NU author(s): Dr Dumitru Sirbu,
Professor Andrew Benniston,
Emeritus Professor Anthony Harriman
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
© 2017 American Chemical Society. Tin(IV) catalysis allows isolation of a boron dipyrromethene derivative bearing a solitary strap around the boron center. The conditions favor internal cyclization without contamination by side products and provide high yields of product in good purity. A phenolate-based strap imposes chirality and causes geometrical distortion of the dipyrrin. Relatively strong fluorescence is observed for single crystals, evaporated films, and adsorbed layers. Single-crystal absorption and emission spectra resemble those observed from solution with contributions from a dimer.
Author(s): Sirbu D, Benniston AC, Harriman A
Publication type: Article
Publication status: Published
Journal: Organic Letters
Print publication date: 07/04/2017
Online publication date: 20/03/2017
Acceptance date: 13/02/2017
ISSN (print): 1523-7060
ISSN (electronic): 1523-7052
Publisher: American Chemical Society
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