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Coinage Metal Complexes of Phosphonite Analogues of 2-Diphenylphosphino-1,1′-binaphthyl (H-MOP) and 2-Diphenylphosphino-2′-methoxy-1,1′-binaphthyl (MeO-MOP)

Lookup NU author(s): James Fleming, Dr Paul Waddell, Dr Mike Probert, Emeritus Professor Bill Clegg, Dr Lee Higham

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Abstract

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim Chiral MOP-phosphonites containing two phenoxy substituents (S)-1a/(R)-1b, a biphenoxy group (S)-2a/(R)-2b or the 3,3′-dimethylbiphenoxy group (S)-3a/(R)-3b, have been coordinated to the coinage metals. Six [Au(LP)Cl] complexes have been prepared and five were characterised by X-ray crystallography, as well as complex [Au{(S)-3a}2]SbF6. Six [Ag(LP)OTf] complexes were synthesised, studied by VT NMR spectroscopy and, in the case of [Ag{(R)-2b}OTf], by X-ray crystallography. Six [Cu(LP)(MeCN)2]PF6 complexes were prepared, and [Cu{(R)-3b}(MeCN)2]PF6 was characterised crystallographically, as was the decomposition product [Cu{(S)-1a}(O2PF2)]2.


Publication metadata

Author(s): Fleming JT, Waddell PG, Probert MR, Clegg W, Higham LJ

Publication type: Article

Publication status: Published

Journal: European Journal of Inorganic Chemistry

Year: 2017

Volume: 2017

Issue: 21

Pages: 2837-2844

Print publication date: 08/06/2017

Online publication date: 27/04/2017

Acceptance date: 27/04/2017

ISSN (print): 1434-1948

ISSN (electronic): 1099-0682

Publisher: Wiley-VCH Verlag

URL: https://doi.org/10.1002/ejic.201700371

DOI: 10.1002/ejic.201700371


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