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Coordination properties of a 2-aryl-1,3,2-dioxaphospholane

Lookup NU author(s): Professor Judith Howard, Dr Mike Probert

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Abstract

© 2018 The coordination properties of the 2-aryl-1,3,2-dioxaphospholane 2,6-(CF3)2C6H3P(OCH2)2 1 (L) have been investigated, by reaction with elemental selenium in solution to form the phosphorus(V) oxidation product 2,6-(CF3)2C6H3P(Se)(OCH2)2 2, and with metal-containing precursors to form three new complexes trans-[PdCl(μ-Cl)(L)]2 3, cis-[PdMe2L2] 4 and [AuCl(L)] 5. All of the metal complexes have been characterised by single-crystal X-ray structure determination.


Publication metadata

Author(s): Coffer PK, Dillon KB, Howard JAK, Probert MR, Shepherd HJ

Publication type: Article

Publication status: Published

Journal: Inorganica Chimica Acta

Year: 2018

Volume: 479

Pages: 24-29

Print publication date: 01/07/2018

Online publication date: 20/04/2018

Acceptance date: 18/04/2018

ISSN (print): 0020-1693

ISSN (electronic): 1873-3255

Publisher: Elsevier BV

URL: https://doi.org/10.1016/j.ica.2018.04.030

DOI: 10.1016/j.ica.2018.04.030


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