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Deoxytrifluoromethylthiolation and Selenylation of Alcohols by using Benzothiazolium Reagents

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

Benzothiazolium salts have been developed as new reagents for installing valuable fluorine-containing functional groups onto organic molecules. The bench-stable and easy-to-handle solid BT-SCF₃ delivered a wide range of alkyl-SCF₃ compounds directly from alcohols under mild conditions, whereas the related selenium derivative BT-SeCF₃ was employed in unprecedented deoxytrifluoromethylselenylation reactions.

Publication metadata

Author(s): Dix S, Jakob M, Hopkinson MN

Publication type: Article

Publication status: Published

Journal: Chemistry - A European Journal

Year: 2019

Volume: 25

Issue: 32

Pages: 7635-7639

Print publication date: 07/06/2019

Online publication date: 13/05/2019

Acceptance date: 10/04/2019

ISSN (print): 0947-6539

ISSN (electronic): 1521-3765

Publisher: Wiley

URL: https://doi.org/10.1002/chem.201901607

DOI: 10.1002/chem.201901607

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