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A Radical Revolution for Trifluoromethoxylation

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

The study of OCF₃-substituted molecules is somewhat hampered by a lack of diverse synthetic methods to access them. By introducing a new mild and practical reaction system for accessing the ^.OCF₃ radical, a recent study by Liu, Ngai, and co-workers has the potential to dramatically expand the scope of direct trifluoromethoxylation. The features of this ground-breaking system are discussed and placed into context with other recent advances on nucleophilic trifluoromethoxylation.

Publication metadata

Author(s): Sahoo B, Hopkinson MN

Publication type: Review

Publication status: Published

Journal: Angewandte Chemie International Edition

Year: 2018

Volume: 57

Issue: 27

Pages: 7942-7944

Print publication date: 26/06/2018

Online publication date: 11/06/2018

Acceptance date: 30/04/2018

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

URL: https://doi.org/10.1002/anie.201804939

DOI: 10.1002/anie.201804939

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