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Diverse Visible-Light-Promoted Functionalizations of Benzotriazoles Inspired by Mechanism-Based Luminescence Screening

Lookup NU author(s): Dr Matt HopkinsonORCiD

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Abstract

Trinity! Three visible-light-promoted functionalization reactions of benzotriazole substrates were discovered using a mechanism-based screening method and provided ortho-thiolated, -borylated, and -alkylated N-arylbenzamide products. The functional group tolerance of the borylation reaction was further analyzed by the first application of an additive-based robustness screen in a photocatalytic transformation.

Publication metadata

Author(s): Teders M, Gómez-Suárez A, Pitzer L, Hopkinson MN, Glorius F

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie International Edition

Year: 2017

Volume: 56

Issue: 3

Pages: 902-906

Print publication date: 10/01/2017

Online publication date: 21/12/2016

Acceptance date: 22/11/2016

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley

URL: https://doi.org/10.1002/anie.201609393

DOI: 10.1002/anie.201609393

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