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Amine-modified polyionic liquid supports enhance the efficacy of PdNPs for the catalytic hydrogenation of CO₂ to formate

Lookup NU author(s): Reece Paterson, Dr Elisabetta Arca, Dr Casey Dixon, Dr Corinne Wills, Dr Kejun Wu, Dr Julian Knight, Dr Simon DohertyORCiD

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Abstract

© 2023 The Royal Society of Chemistry. Palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid is a remarkably active catalyst for the hydrogenation of CO₂ to formate; the initial TOF of 500 h−1 is markedly higher than either unmodified catalyst or its benzylamine and N,N-dimethylaniline modified counterparts and is among the highest to be reported for a PdNP-based catalyst.

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Author(s): Paterson R, Fahy LE, Arca E, Dixon C, Wills CY, Yan H, Griffiths A, Collins SM, Wu K, Bourne RA, Chamberlain TW, Knight JG, Doherty S

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2023

Volume: 59

Pages: 13470-13473

Online publication date: 23/10/2023

Acceptance date: 17/10/2023

Date deposited: 09/11/2023

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: https://doi.org/10.1039/d3cc04987f

DOI: 10.1039/d3cc04987f

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