Lookup NU author(s): Dr Michael Hall
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A variety of routes are described for the synthesis of α-silyloxy aldehydes in which the silicon atom bears a prenyl side chain. These compounds are shown to undergo stereoselective carbonyl ene cyclisation under mildly Lewis acidic conditions and the derived silacycles are cleaved to afford single diastereomers of functionalised triols.
Author(s): Hall MJ; Robertson J; Stafford PM; Green SP
Publication type: Article
Publication status: Published
Journal: Organic & Biomolecular Chemistry
ISSN (print): 1477-0520
ISSN (electronic): 1477-0539
Publisher: Royal Society of Chemistry
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