Toggle Main Menu Toggle Search

Open Access padlockePrints

Tetraphenoxoborate complexes of barium: Crystal structures of the metalloborates [Ba(thf)4{B(OPh)4}2] and [Ba(dme)2{B(OPh)4}2]

Lookup NU author(s): Dr John ErringtonORCiD, Dr Gary Walker, Emeritus Professor Bill CleggORCiD, Dr Lynne Horsburgh

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

The new molecular phenoxides [BaB2(OPh)8(thf)4] 1 and [BaB2(OPh)8(dme)2] 2 have been synthesised from B(OPh)3 and either a preformed barium phenoxide or barium metal in the presence of phenol; X-ray structure determinations reveal that the barium is eight-coordinate in both compounds and that the chelating [B(OPh)4]- groups occupy trans positions in 1 but cis positions in 2.


Publication metadata

Author(s): Errington RJ, Tombul M, Walker GLP, Clegg W, Heath SL, Horsburgh L

Publication type: Article

Publication status: Published

Journal: Journal of the Chemical Society - Dalton Transactions

Year: 1999

Issue: 20

Pages: 3533-3534

Print publication date: 21/10/1999

ISSN (print): 1472-7773

ISSN (electronic): 1364-5447

Publisher: The Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/a906089h

DOI: 10.1039/a906089h


Altmetrics

Altmetrics provided by Altmetric


Share