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Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Keith Izod, Dr Stephen Liddle
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Thermal treatment of [Sm{P(CH[SiMe3]2)(C6H4-2-CH 2NMe2)}2(THF)] (2) under reduced pressure for several hours leads to complete de-solvation and isolation of the homoleptic phosphide complex [Sm{P(CH[SiMe3]2)(C6H4-2-CH 2NMe2)}2] (3). X-ray crystallography shows complex 3 to be monomeric, with a four-coordinate, distorted tetrahedral Sm(II) center. The close contacts between Sm and the ipso-carbon atoms of the ligands observed in 2 are absent in 3. © 2000 Elsevier Science B.V. All rights reserved.
Author(s): Clegg W, Izod K, Liddle ST
Publication type: Note
Publication status: Published
Journal: Journal of Organometallic Chemistry
Year: 2000
Volume: 613
Issue: 1
Pages: 128-131
ISSN (print): 0022-328X
ISSN (electronic): 1872-8561
URL: http://dx.doi.org/10.1016/S0022-328X(00)00510-6
DOI: 10.1016/S0022-328X(00)00510-6
