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Synthesis, structure and coordination chemistry of mono- and bis-heterocyclic-ferrocenyl derivatives

Lookup NU author(s): Clayton Price, Dr Ben Horrocks, Professor Andrew Houlton, Dr Mark Elsegood, Emeritus Professor Bill Clegg

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Abstract

The heterocyclic-ferrocenyl derivatives, 1,1′-bis(5-phenanthridine)ferrocene (1) and [Pd{(η5-C5H5)Fe(η5-C 5H3(phenanthroline))}Cl] (2), have been prepared and characterised by single-crystal X-ray analyses. These confirm that in 1 the substitution at the heterocycle is ortho to the nitrogen atom of the phenanthridine while for 2 ortho-metallation of the ferrocenyl group is observed in addition to chelation of the Pd(II) by the phenanthroline moiety. © 2000 Elsevier Science S.A.


Publication metadata

Author(s): Isaac CJ, Price C, Horrocks BR, Houlton A, Elsegood MRJ, Clegg W

Publication type: Article

Publication status: Published

Journal: Journal of Organometallic Chemistry

Year: 2000

Volume: 598

Issue: 2

Pages: 248-253

ISSN (print): 0022-328X

ISSN (electronic): 1872-8561

Publisher: Elsevier

URL: http://dx.doi.org/10.1016/S0022-328X(99)00717-2

DOI: 10.1016/S0022-328X(99)00717-2


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