Lookup NU author(s): Dr Simon Doherty,
Dr Edward Robins,
Dr Julian Knight,
Paul Anthony Champkin,
Emeritus Professor Bill Clegg
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The synthesis of a new class of 1,4-bis(diphenylphosphino)-1,3-butadiene was discussed. Catalyst mixtures based on 1,2,3,4-Ph4-NUPHOS were found to be superior to those based on BINAP, with activities of 6900 and 260 (mol of product) (mol of palladium)-1h-1 respectively. The applications in palladium catalyzed cross-coupling reactions were also discussed.
Author(s): Doherty S, Robins EG, Nieuwenhuyzen M, Knight JG, Champkin PA, Clegg W
Publication type: Article
Publication status: Published
ISSN (print): 0276-7333
ISSN (electronic): 1520-6041
Publisher: American Chemical Society
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