Lookup NU author(s): Dr Julian Knight,
Dr Kirill Tchabanenko
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The stereoselective synthesis of piperidine alkaloids deoxymannojirimycin and D-mannolactam from D-serine has been achieved. The key step involves palladium-catalysed decarboxylative carbonylation of a serine-derived 5-vinyloxazolidin-2-one to give 6-(tert-butyldimethylsilyloxymethyl)-3,6-dihydro-1H-pyridin-2-one which was subsequently converted into the title compounds. © 2003 Elsevier Science Ltd. All rights reserved.
Author(s): Knight JG, Tchabanenko K
Publication type: Article
Publication status: Published
ISSN (print): 0040-4020
ISSN (electronic): 1464-5416
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