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An axial met ligand at a type 1 copper site is preferable for fast electron transfer

Lookup NU author(s): Dr Dr MD Harrison Harrison, Professor Christopher Dennison

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Abstract

Rapid fire! The replacement of the axial oxygen ligand at the type 1 copper site of stellacyanin with a weakly interacting thioether sulfur results in a fivefold increase in the electron self-exchange rate constant. This provides the first example of a type 1 copper site variant that exhibits increased reactivity and demonstrates that a site with an axial Met ligand is preferable for fast electron transfer, as shown.


Publication metadata

Author(s): Harrison MD, Dennison C

Publication type: Article

Publication status: Published

Journal: ChemBioChem

Year: 2004

Volume: 5

Issue: 11

Pages: 1579-1581

ISSN (print): 1439-4227

ISSN (electronic): 1439-7633

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/cbic.200400152

DOI: 10.1002/cbic.200400152

PubMed id: 15515093


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