Toggle Main Menu Toggle Search

Open Access padlockePrints

Structural chemistry of halogenated monocarbaboranes: The extended structures of Cs[1-HCB9H4Br5], Cs[1-HCB 11H5Cl6] and Cs[1-HCB11H5Br6]

Lookup NU author(s): Emeritus Professor Bill CleggORCiD

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

The crystal structures of the Cs+ salts of the halogenated monocarbaborane anions [closo-1-HCB9H4Br5] -, [closo-1-HCB11H5Cl6]- and [closo-1-HCB11H5Br6]- have been determined. The structures show two-dimensional extended-sheet or three-dimensional lattice structures and feature unusual distorted cuboctahedral and tetrakis hexahedral coordination geometries about Cs+. Incidental to the structural work, new convenient preparations of the precursive non-halogenated monocarbaborane anions [closo-1-HCB9H 9]- and [closo-1-HCB11H11] - are presented.


Publication metadata

Author(s): Franken A, Bullen NJ, Jelinek T, Thornton-Pett M, Teat SJ, Clegg W, Kennedy JD, Hardie MJ

Publication type: Article

Publication status: Published

Journal: New Journal of Chemistry

Year: 2004

Volume: 28

Issue: 12

Pages: 1499-1505

ISSN (print): 1144-0546

ISSN (electronic): 1369-9261

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b410929e

DOI: 10.1039/b410929e


Altmetrics

Altmetrics provided by Altmetric


Share