ePrints

Structure and phase behavior of a 2:1 complex between arene- and fluoroarene-based conjugated rigid rods

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Professor Todd Marder

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

The πs have it: An unusual 2:1 areneperfluoroarene π complex is formed between 1,4-bis(phenylethynyl)benzene and its perfluorinated analogue, and this is the first example of a non-1:1 complex of this type. The interstack geometry (see picture; red H, green F) is also unusual, as is the complex mesomorphism of this system.

Publication metadata

Author(s): Watt SW, Dai C, Scott AJ, Burke JM, Thomas RLl, Collings JC, Viney C, Clegg W, Marder TB

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie

Year: 2004

Volume: 43

Issue: 23

Pages: 3061-3063

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200453828

DOI: 10.1002/anie.200453828

Altmetrics

Share