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Seeing soil carbon: Use of thermal analysis in the characterization of soil C reservoirs of differing stability

Lookup NU author(s): Professor David Manning, Dr Elisa Lopez-Capel

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Abstract

To understand the rates of turnover of soil carbon, and hence interactions between soil carbon pools and atmospheric CO2 levels, it is essential to be able to quantify and characterize soil organic matter and mineral hosts for C. Thermal analysis is uniquely suited to this task, as different C compounds decompose during a heating cycle at different temperatures. In 'air' (80% He or N2, 20% O2), relatively labile cellulosic material decomposes between 300 and 350°C and more refractory lignin and related materials decompose between 400 and 650°C. Calcite and other common soil carbonate minerals decompose at 750-900°C. Using thermal analysis connected to a quadrupole mass spectrometer and to an isotope ratio mass spectrometer, it is possible to simultaneously determine mass loss during combustion, evolved gas molecular compositions, and carbon isotope ratios for evolved CO2. As an example of the potential of the technique, the evolution of a fungally-degraded wheat straw shows initial isotopic heterogeneity consistent with its plant origins (-23.8‰ v-PDB for cellulosic material; -26.1‰ v-PDB for ligninic material), which homogenizes at heavier δ 13C values (-21.0‰ v-PDB) as lignin is preferentially degraded by fungal growth. Simultaneously, it is shown that the evolution of nitrogen compounds is initially dominated by decomposition of aliphatic N within the cellulosic component, but that with increasing fungal degradation it is the ligninic component that contributes N to evolved gases, derived presumably from pyrrolic and related N groups produced during soil degradation through condensation reactions. Overall, the use of thermal analysis coupled to quadrupole and stable isotope mass spectrometry appears to have considerable potential for the characterization of discrete carbon pools that are amenable to the modelling of carbon turnover within soil systems. © 2005 The Mineralogical Society.


Publication metadata

Author(s): Manning DAC, Lopez-Capel E, Barker S

Publication type: Article

Publication status: Published

Journal: Mineralogical Magazine

Year: 2005

Volume: 69

Issue: 4

Pages: 425-435

Print publication date: 01/08/2005

ISSN (print): 0026-461X

ISSN (electronic): 1471-8022

Publisher: Mineralogical Society

URL: http://dx.doi.org/10.1180/0026461056940260

DOI: 10.1180/0026461056940260


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