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Taming a functional group: Creating air-stable, chiral primary phosphanes

Lookup NU author(s): Dr Lee Higham

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Abstract

No rings of fire! Enantiopure primary phosphanes have been developed which are remarkably stable to air oxidation in both solid and solution states (see example). This new class of stable ligand synthon appears to owe its stability to conjugation in their aryl backbones with the extended it ring system. Even one extra ring is good enough. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.


Publication metadata

Author(s): Hiney RM, Higham LJ, Muller-Bunz H, Gilheany DG

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie International Edition

Year: 2006

Volume: 45

Issue: 43

Pages: 7248-7251

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/anie.200602143

DOI: 10.1002/anie.200602143

PubMed id: 17022105


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