Lookup NU author(s): Dr Michael Hall
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
Silatropic carbonyl ene cyclisations of β-(allylsilyloxy)- and β-(crotylsilyloxy)butyraldehydes are shown to proceed with high stereoselectivity but at a much reduced rate in comparison to the cyclisation of analogous α-substrates. In the second section, olefin cross-metathesis is explored as a route to substituted α-(allylsilyloxy)aldehydes and the method applied to the synthesis of diastereomeric 2-deoxy- and 2-deoxy-2-C-phenyl hexose derivatives from butanediacetal-protected d-glyceraldehyde. © The Royal Society of Chemistry 2008.
Author(s): Robertson J, Green SP, Hall MJ, Tyrrell AJ, Unsworth WP
Publication type: Article
Publication status: Published
Journal: Organic and Biomolecular Chemistry
Print publication date: 01/01/2008
ISSN (print): 1477-0520
ISSN (electronic): 1477-0539
Publisher: Royal Society of Chemistry
Altmetrics provided by Altmetric