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Regioselective addition of tert-BuN C to the alpha carbon atom of the allenyl ligand in [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(2)(alpha,beta)-(H)C-alpha=C-beta=C gamma H2}]: Formation of [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(1)-(tert-BuN C)C=CCH3}] and [Fe-2(CO)(6)(mu-PPh2)(mu-eta(1):eta(2)-{tert-BuNHC(O)CH2}C=CH2)] via competitive 1,3-hydrogen migration and hydrolysis of the reactive allene-bridged intermediate [Fe-2(CO)(6)(mu-PPh2){mu-eta(1):eta(1)-(tert-BuNC)HC=C=CH2}]

Lookup NU author(s): Dr Simon Doherty, Mark Waugh, Thomas Scanlan, Emeritus Professor Bill Clegg, Dr Mark Elsegood


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Publication metadata

Author(s): Doherty S, Hogarth G, Waugh M, Scanlan TH, Clegg W, Elsegood MRJ

Publication type: Article

Journal: Organometallics

Year: 1999

Volume: 18

Issue: 16

Pages: 3178-3186

Print publication date: 10/07/1999

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society


DOI: 10.1021/om9901630


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