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Aluminium(salen) and Tetrabutylammonium Bromide Catalysed Synthesis of Cyclic Di- and Trithiocarbonates from Epoxides and Carbon Disulfide

Lookup NU author(s): Professor Michael North, Dr Pedro Villuendas

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Abstract

The combination of a bimetallic aluminium(salen) complex and tetrabutylammonium bromide was found to catalyse the synthesis of cyclic di- and trithiocarbonates from epoxides and carbon disulfide. Reactions carried out at 50 degrees C produced 1,3-oxathiolane-2-thiones, whilst at 90 degrees C, 1,3-dithiolane-2-thiones were formed.

Publication metadata

Author(s): North M, Villuendas P

Publication type: Article

Publication status: Published

Journal: Synlett

Year: 2010

Issue: 4

Pages: 623-627

Print publication date: 01/03/2010

ISSN (print): 0936-5214

ISSN (electronic): 1437-2096

Publisher: Georg Thieme Verlag

URL: http://dx.doi.org/10.1055/s-0029-1219160

DOI: 10.1055/s-0029-1219160

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