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An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation

Lookup NU author(s): Dr Simon Doherty, Dr Julian Knight, Jack Ellison, Dr Ross Harrington

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Abstract

Ring Opening Metathesis Polymerisation (ROMP) of pyrrolidinium-functionalised norbornene-based monomers with cyclooctene has been used to prepare linear cation-decorated polymer supports with tuneable surface properties and microstructure. The derived peroxophosphotungstate-based polymer immobilised ionic liquid phase (PIILP) catalyst is an efficient and recyclable system for the epoxidation of allylic alcohols and alkenes, with only a minor reduction in performance on successive cycles.


Publication metadata

Author(s): Doherty S, Knight JG, Ellison J, Weekes D, Harrington RW, Hardacre C, Manyer H

Publication type: Article

Journal: Green Chemistry

Year: 2012

Volume: 14

Issue: 4

Pages: 925-929

Print publication date: 01/04/2012

ISSN (print): 1463-9262

ISSN (electronic): 1463-9270

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/C2GC16679H

DOI: 10.1039/C2GC16679H


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