Lookup NU author(s): Arne Ficks,
Dr Ross Harrington,
Dr Lee Higham
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
Chiral phosphonite ligands (S,Rb)-5a, (S,Sb)-5b, (R,Rb)-6a and (R,Sb)-6b are introduced, comprising a MOP-type backbone with a binol-based binaphthyl group bound to the phosphorus. Their reaction with [Pd(η3-C4H7)Cl]2 affords η3-methallylpalladium chloride complexes 7a/b and 8a/b which have been isolated and structurally characterised. Solid-state and solution studies indicate subtle differences in their coordination behaviour, which ultimately affects their efficacy in the asymmetric hydrosilylation of styrene.
Author(s): Ficks A, Hiney RM, Harrington RW, Gilheany DG, Higham LJ
Publication type: Article
Journal: Dalton Transactions
Print publication date: 03/02/2012
ISSN (print): 1477-9226
ISSN (electronic): 1477-9234
Publisher: Royal Society of Chemistry
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