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Regioselective Addition of tert-BuNC to the α Carbon Atom of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η1:η2α,β-(H)CαCβCγH2}]: Formation of [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)CCCH3}] and [Fe2(CO)6(μ-PPh2)(μ-η1:η2-{tert-BuNHC(O)CH2}CCH2)] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)HCCCH2}]

Lookup NU author(s): Dr Simon Doherty, Mark Waugh, Thomas Scanlan, Emeritus Professor Bill Clegg, Dr Mark Elsegood

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Publication metadata

Author(s): Doherty S, Hogarth G, Waugh M, Scanlan TH, Clegg W, Elsegood MRJ

Publication type: Article

Journal: Organometallics

Year: 1999

Volume: 18

Issue: 16

Pages: 3178-3186

Print publication date: 02/08/1999

ISSN (print): 0276-7333

ISSN (electronic): 1520-6041

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/om9901630

DOI: 10.1021/om9901630


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